Which of the following compound contain most electronegative carbon atom?
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a
CH3−CH3
b
CH2=CH2
c
CH≡CH
d
CH4
answer is C.
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Detailed Solution
Step - 1Electronegativity of carbon atom depend upon the % s-character.More the % s-character more is the electronegativity of carbon atom.Step - 2in option (1) CH3-CH3 two carbons are SP3 % s-character is 25%.Step - 3in option (2) CH2=CH2 two carbons are SP2 % s-character is 33%.in option (3) CH≡CH two carbons are SP % s-character is 50%. it contains more electronegative carbon atoms.[Step 5]:in option (4) CH4 carbon is SP3 % s-character is 25%.