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Q.

Which of the following compound give yellow precipitate with I2 and NaOH?

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a

CH3CH2OH

b

CCl3CHO

c

CH3CH2CH2OH

d

C3H7CHO

answer is A.

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Detailed Solution

Ethyl alcohol gives positive iodoform test (i.e. yellow ppt. with I2 and NaOH)CH3CH2OH+4I2+6NaOH→CHI3yellow ppt.+5NaI+CH3COONa+3H2O
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