Q.

In which of the following compounds, the C-Cl bond ionisation shall give most stable carbonium ion?

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a

b

c

d

answer is D.

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Detailed Solution

is most stable due to hyperconjugation. primary benzyl carbocation stabilizes through resonance but less stable than tertiary butyl carbocation……secondary and tertiary benzyl carbocations are more stable than tertiary butyl carbocation
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