Which of the following compounds reacts fastest with Lucas reagents?
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a
1-Butanol
b
2-Butanol
c
2-Methyl-2-propanol
d
2-Methyl-1-propanol
answer is C.
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Detailed Solution
Alcohols are soluble in Lucas reagent(conc. HCl and ZnCl2 ) while their halides are immiscible and produce turbidity in solution. In case of tertiary alcohols turbidity produce immediately while primary alcohols do not. So Rate of reaction with Lucas reagent is : 30>20>10 .