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Q.

Which of the following is correct?

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a

During N2+formation, one electron is removed from the bonding molecular orbitals.

b

During O2+ formation, one electron is removed from the antibonding molecular orbitals.

c

During O2− formation, one electron is added to the bonding molecular orbitals.

d

During CN- formation, one electron is added to the bonding molecular orbitals.

answer is A.

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Detailed Solution

n≤14σ1s2,σ∗1s2,σ2s2,σ∗2s2π2py2π2pz2,σ2px2,π2py∗,π2pz∗⇒e−is removed from BMO (2) n>14 σ1s2,σ∗1s2,σ2s2,σ∗2s2,σ2px2 π2py2,π2pz2,π∗2py1,π∗2pz1⇒e−is removed from ABMOπ2pz(3) e−will be added in ABMO (4) e−will be added in BMO
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