Q.

Which of the following is correct increasing order of boiling point  ?

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answer is 4.

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Detailed Solution

Chained alkanes fit perfectly in a given space and make up to high mass and density. Whereas branching increases then they are no effective packing and more voids are made. This results in poor attraction and packing, if number of branches increases B.P decreases.
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Which of the following is correct increasing order of boiling point  ?