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Q.

Which of the following is correct order of reactivity by SN2 mechanism

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a

1-bromobutane > 2-bromobutane

b

2-bromobutane > 2-bromo-2-methyl butane

c

C−C−C−C−Br>C−C−C−C−Br | | C C

d

All are correct

answer is D.

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Detailed Solution

(1) 1oRX>2oRX steric hindrance in 1oRX<2oRX(2) 2oRX>3oRX steric hindrance in 2oRX<3oRX(3) C−C−C−C−Br>C−C−C−C−Br | | C CCarbon side chain distance from halogen increases reactivity withrespective to SN2 increasesAll are correct

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