Which of the following is the correct order of solubility in water ?
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a
BaSO4 > Sr SO4 > CaSO4 > MgSO4
b
BaSO4 > MgSO4 > SrSO4 > CaSO4
c
MgSO4 > CaSO4 > SrSO4 > BaSO4
d
MgSO4 > BaSO4 > CaSO4 > Sr SO4
answer is C.
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Detailed Solution
As hydration energy decreases solubility decreasesIf anion size is large SO4-2,CO3-2 with small change in cation size there is no considerable change in lattice energy and hence in this case solubility depends an hydration energy.As size of cation increases hydration energy decreases. Therefore solubility decreasesHydration energy α Solubility (no considerable change in lattice energy)