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Q.

Which of the following is the correct order of the thermal stability of hydrides

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a

NH3>PH3>AsH3>SbH3>BiH3

b

PH3>NH3>AsH3>SbH3>BiH3

c

BiH3>SbH3>NH3>AsH3>PH3

d

NH3>BiH3>SbH3>AsH3>PH3

answer is A.

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Detailed Solution

Thermal stability decreases down the group due to increase in bond length (M-H) down the group and bond strength (M-H) decreases down the group.
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