Which of the following is the correct set of volume calculated by ideal gas equation and van der Waals equation respectively for 1 mole CO2 gas at 300 K and 10 atm pressure. (R = 0.0821 L atm K-1 mol-1)
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a
2.463 L, 2.56 L
b
2.463 L, 2.38 L
c
2.463 L, 2.463 L
d
2.463 L, 2.5 L
answer is B.
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Detailed Solution
V1=nRTp=1 × 0.0821 × 30010= 2.463 L For CO2, at 10 atm Z < 1 ⇒ VRV1<1 ⇒VR < V1