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Q.

Which of the following is correct for a solution showing positive deviations from Raoult's law?

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a

ΔV=+ve,ΔH=+ve

b

ΔV=-ve,ΔH=-ve

c

ΔV=+ve,ΔH=-ve

d

ΔV=-ve,ΔH=+ve

answer is A.

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Detailed Solution

ΔHmix>0, endothermic dissolution, heat is absorbed. ΔVmix>0, volume increased after dissolution
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