Which of the following does not decolourise iodine?
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a
Na2SO3
b
NaCl
c
Na2S2O3
d
NaOH
answer is B.
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Detailed Solution
In (1), (3) and (4), l2 is reduced to 2I⊖ but Cl- ion cannot displace I2 but Cl2 can displace I⊖ion. (1) I2+SO32−+H2O⟶2I⊖+SO42−+2H⊕ (3) I2+2S2O32−⟶S4O62−+2I⊖ (4) I2+2OH⊖⟶IO⊙+I⊖+H2O