Q.
Which of the following is an example of pseudo unimolecular reaction?
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a
CH3COOCH3+H2O →H+CH3COOH+CH3OH
b
CH3COOCH3+H2O→OH−CH3COOH+CH3OH
c
2FeCl3+SnCl2→SnCl4+2FeCl2
d
NaOH+HCl→NaCl+H2O
answer is A.
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Detailed Solution
When in any chemical reaction, one of the reactant is present in large excess, then the second-order reaction becomes first-order reaction and is known as pseudo unimolecular reaction e.g., CH3COOCH3+H2O→H+CH3COOH+CH3OHin this reaction molecularity is 2 but order of reaction is found to be first order experimentally, so it is an example of pseudo unimoelcular reaction.
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