Q.
Which of the following expressions represent the EMF of the above cell at 25°C?
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a
E=0.05922log aPb2+RHS aPb2+LHS
b
E=0.05922log aPb2+LHS aPb2+RHS
c
E=0.05922logKspPbI21/3
d
E=0.05922logKspPbI2KspPbSO4
answer is A.
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Detailed Solution
Pb(s)(I)PbSO4 PbI2(II)Pb(s) Pb⟶Pb12++2e− (oxidation)PbII2++2e−⟶Pb (Reduction) Net cell reaction: Pb𝕀2+⟶Pb12+Ece𝕀𝕀=Ecell′−0.0592nlogPb2+IPb2+II [Nernst's equation] Ecell°=0, ∴ Ecell=0.0592nlogPb2+IIPb2+I
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