Q.
Which of the following facts about the complex CrNH36Cl3 is wrong?
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a
The complex involves d2sp3 hybridization and is octahedral in shape
b
The complex is paramagnetic
c
The complex is an outer orbital complex
d
The complex gives white precipitate with silver nitrate solution.
answer is C.
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Detailed Solution
ln [Cr(NH3)6]3+, Cr exists as Cr3+ ion. The outer orbital electronic configuration of Cr is 3d3 4s0. The orbital diagram is represented byHere, X indicates lone pair of NH3 donated to Cr. Hence,(a) d2sp3-hybridization, octahedral. Thus, correct.(b) There are three unpaired electrons, hence paramagnetic. Thus, correct.(c) d2sp3-inner orbital complex, thus incorrect.(d) Due to ionizable Cl- ions, white precipitate with AgNO3, thus correct.Therefore, (3) is wrong.
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