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Q.

Which of the following group (s) increases basic strength of substituted aniline?

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a

-OCH3

b

-CH3

c

-SO3H

d

Both (a) and (b)

answer is D.

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Detailed Solution

In case of substituted aniline, electron releasing groups like OCH3,CH3 increase basic strength whereas, electron withdrawing groups like -NO2-SO3H,-COOH,-X decrease the basic strength.
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Which of the following group (s) increases basic strength of substituted aniline?