First slide

Alkyl halides

Question

Which of the following halides will be most reactive in SN² reaction and SN¹ reaction, respectively?

Moderate

A

(I), (II)
B

(II), (I)
C

(I), (IIl)
D

(III), (I)

Solution

$(I) \Rightarrow 1^{\circ}$ allylic halide and less steric hindrance, hence SN²
$(III) \Rightarrow 3^{\circ}$ allylic halide, most stable carbonium ion and SN¹

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