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Q.

Which of the following has least freezing point?

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a

1% sucrose

b

1% NaCl

c

1% CaCl2

d

1% glucose

answer is C.

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Detailed Solution

Depression in freezing point is a colligative property (i.e. depends only upon the number of particles of solutes). Thus, the compound which produces maximum number ofions will have the least freezing point.∴Concentration is same                  Sucrose →No ions NaCl     →Na+ +Cl-⏟                     Two ions                 CaCl2→     Ca2+2Cl-⏟                    Three ions                Glucose → No ions Thus, 1%  CaCl2 will have the least freezing point.
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Which of the following has least freezing point?