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Q.

Which of the following hydrate isomer of CrCl3 .6H20 absorb shorter wavelength in visible spectrum ?

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a

CrH2O6Cl3

b

CrClH2O5Cl2⋅H2O

c

CrCl2H2O4Cl⋅2H2O

d

CrCl3H2O3⋅3H2O

answer is A.

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Detailed Solution

Splitting energy ∝Δabs∝1λabsH2O has more splitting energy than Cl−, therefore CrH2O6Cl3 absorbs shorter wave length.
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