Which of the following is incorrect on the basis of the above Ellingham diagram for carbon?
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a
Up to 710oC, the reaction of formation of CO2, is energetically more favourable, but above 710oC the formation of CO is preferred.
b
In principle, carbon can be used to reduce any metal oxide at a sufficiently high temperature.
c
ΔSC(s)+1/2O2(g)⟶CO(g)<ΔSC(s)+O2(g)⟶CO2(g)
d
Carbon reduces many oxides at elevated temperature because ∆fG⊝ vs temperature line has a negative slope.
answer is C.
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Detailed Solution
In Ellingham diagram, higher is the slope higher is the entropy change so ΔS(C(s)+1/2O2(g)⟶CO(g))>ΔS(C(S)+O2(g)⟶CO2(g)as CO have higher slope.Also, Carbon monoxide is a more effective reducing agent than carbon below 983 K but above this temperature the reverse is true.