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Q.

Which of the following liquid pairs shows a positive deviation  from Raoults law ?

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a

water - hydrochloric acid

b

Acetone - Chloroform

c

water - nitric acid

d

Benzene - methanol

answer is D.

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Detailed Solution

Benzene (non polar) and CH3OH  (polar). Intermolecular interaction between then in solution is  weak.
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Which of the following liquid pairs shows a positive deviation  from Raoults law ?