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Q.

Which of the following makes PCl5 highly reactive?

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a

Hybridisation sp3d

b

Trigonal bipyramidal shape and geometry

c

Division of sites to axial and equitorial positions.

d

Higher P—Cl bond length of axial sites than equitorial and high repulsion of equitorial shared pairs of electrons on axial shared pairs of electrons.

answer is D.

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Detailed Solution

PCl5 is highly reactive due to repulsions between axial  and equatorial shared pair of electrons.
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