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Q.

Which of the following molecular/atomic orbitals have gerade symmetry or center of symmetry?

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a

π* py

b

dxy

c

pz

d

σpx

answer is A.

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Detailed Solution

Orbitals with a center of symmetry have even (gerade) symmetry with respect to inversion, i.e. if the coordinates are inverted so that (x,y,z)→(−x,−y,−z), the orbital is coincident with itself exactly.Orbitals without such a thing have odd (ungerade) symmetry with respect to inversion.
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