In which of the following molecule, bond angle is greater than 109.280
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a
CH3-OH
b
CH33N
c
C6H5-OH
d
CH3-O-CH3
answer is D.
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Detailed Solution
Bond angle in dimethyl ether is 111.70;Due to the repulsions between the two methyl groups, bond angle increases in order to releive angle strain.Thus steric repulsions get minimized;