Which of the following is the most likely structure of CrCl3.6H2O, if 1/3 of total chlorine of the compound is precipitated by adding AgNO3 to its aqueous solution:
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a
CrCl3.6H2O
b
CrH2O3Cl3H2O3
c
CrCl2H2O4ClH2O
d
CrCl.H2O5Cl2H2O
answer is C.
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Detailed Solution
CrCl2H2O4Cl.2H2O↓AgNO3AgCl ppt.Only one chloride ion is present out of coordination sphere. Only those ions that are present out of coordination sphere participate in precipitation.