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Q.

Which of the following is non benzenoid aromatic hydro carbon?

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a

Benzene

b

Napthalene

c

Anthracene

d

Azulene

answer is D.

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Detailed Solution

[Step 1]:Conditions for aromaticityi) Cyclic structureii) Conjugated systemiii) Resonanceiv) Planar (or) almost planarv) (4n+2) π – electrons  i.e Huckel rule Where n = 0, 1, 2, 3. . . . . . . .[Step 2]:are Benzenoid aromatic hydrocarbons.Whereas Azulene  is aromatic but not having benzene ring.
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