Q.
Which of the following is not correct for PCl5 ?
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a
Geometry and shape are trigonal bipyramidal
b
Hybridization of P-atom is sp3d
c
All P-Cl bond lengths are equal
d
In solid state it exists as [PCl4]+ [PCl6]–
answer is C.
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Detailed Solution
PCl5 has trigonal bipyramidal geometry and shape with two P-Cl axial longer bonds than other three P-Cl equatorial bonds.
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