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Which of the following is not correct for PCl5 ?

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By Expert Faculty of Sri Chaitanya
a
Geometry and shape are trigonal bipyramidal
b
Hybridization of P-atom is sp3d
c
All P-Cl bond lengths are equal
d
In solid state it exists as [PCl4]+ [PCl6]–
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detailed solution

Correct option is C

PCl5 has trigonal bipyramidal geometry and shape with two P-Cl axial longer bonds than other three P-Cl equatorial bonds.


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In solid state PCl5 is a :

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