Q.

Which of the following is not hydrolysed easily?

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a

CCl4

b

SiCl4

c

GeCl4

d

SnCl4

answer is A.

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Detailed Solution

CCl4 does not undergo hydrolysis via SN2 due to absence of d-orbitals in carbon atom. However, it undergoes hydrolysis via SN1 at elevated temperatures. SiCl4 undergoes Hydrolysis due to the presence of vacant d-orbitals in silicon atom
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