Questions
Which of the following is not hydrolysed easily?
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By Expert Faculty of Sri Chaitanya
a
CCl4
b
SiCl4
c
GeCl4
d
SnCl4
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Correct option is A
CCl4 does not undergo hydrolysis via SN2 due to absence of d-orbitals in carbon atom. However, it undergoes hydrolysis via SN1 at elevated temperatures. SiCl4 undergoes Hydrolysis due to the presence of vacant d-orbitals in silicon atom
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