Q.
Which of the following is not true
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a
Ordinary water is electrolysed more rapidly than D2O
b
Reaction between H2 and Cl2 is much faster than D2 and Cl2
c
D2O freezes at lower temperature than H2O
d
Bond dissociation energy for D2 is greater than H2
answer is C.
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Detailed Solution
Physical Constants : D2O > H2OReason, Due to high molecular weight of D2O[20] than that of H2O.Molecular mass ∞Physical constantsException Dielectric constant (D)[Dielectric const] D : H2O > D2O→ Ordinary water is electrolysed more rapidly than D2OReason ; Dielectric constant of water [DH2O] > Dielectric constant of D2O[DD2O]Note : Dielectric constant is the ability of a solvent to ionise the bond of a salt.Higher the dielectric constant higher will be the ionisation ability.→ Bond Dissociation energy :As bond dissaciation energy ↓es reactivity with Cl2 ↑es.
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