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Which of the following pair of group 13 elements have similar atomic radius

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By Expert Faculty of Sri Chaitanya
a
B,Al
b
In, Tl
c
Ga,In
d
B,Tl

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detailed solution

Correct option is B

Atomic radius order :Tl~In >Al > Ga > B                           OR                         B < Ga < Al < In ~ Tl"In,Tl"have almost all same atomic radii,due to poor shielding effect by innershell f-electrons and d-electrons the valency shell electrons in "Tl" are strongly attracted by nucleus and hence the sizes of "In" and " Tl " are almost all same.


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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