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Q.

In which of the following pairs both the complexes have same geometry ?

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a

NiCl42−,Ni(CN)42−

b

CoF63−,CoNH363+

c

CuNH34+,NiNH342+

d

Ni(CO)4,Ni(CN)42−

answer is B.

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Detailed Solution

(a) NiCl42−,Ni(CN)42− Hybr. sp3, dsp2  Geometry-Tetrahedral, square planar  (b) CoF63−,CoNH363+ Hybr. sp3d2,d2sp3 Geometry−octahedral, octahedral.  (c) CuNH34+,NiNH342+ Hybr. sp3, Geometry−Tetrahedral, square planar.  (d) Ni(CO)4,Ni(CN)42− Hybr. sp3, dsp2 Geometry−Tetrahedral, square planar.
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