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Q.

In which of the following process ∆H and ∆U are of same magnitude.

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a

Evaporation of CCl4(l)

b

CaCO3(s)⟶CaO(s)+CO2(g)

c

NH4Cl(s)⟶NH4Cl(g)

d

2HI(g)⟶H2(g)+I2(g)

answer is D.

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Detailed Solution

ΔH=ΔU+ΔnRTΔn=nP−nR=0∴ΔH=ΔU
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