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Q.

In which of the following reaction of aniline, the benzene nucleus of aniline is not attacked by the reagent

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a

reaction with  bromine water

b

reaction with acetyl chloride in presence of pyridine

c

reaction with conc. Sulphuric acid at 453K

d

reaction with nitration mixture

answer is B.

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Detailed Solution

Ph-NH2 +CH3COCl  →PyridinePh-NHCOCH3 +HCl it is an example of N- acylation
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