Q.

In which of the following reactions, the equilibrium remains unaffected on addition of small amount of argon at constant volume?

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a

b

c

d

The equilibrium will remain unaffected in all the three cases

answer is D.

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Detailed Solution

Addition of inert gas at constant volume has no affect on equilibrium stateVolume is kept constant, none of the reactants (or) products are neither added nor removed equilibrium state remains unaffected.Alternatlywhen volume is constant and inert gas is added concentration of all reactants and products remains same.
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