Q.

Which of the following reactions show(s) heterogeneous equilibria?

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a

N2(g)+3H2(g)⇌2NH3(g)

b

H2O(l)⇌H2O(g)

c

CaCO3(s)⇌ΔCaO(s)+CO2(g)

d

Both (b) and (c)

answer is D.

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Detailed Solution

The equilibrium between water vapour and liquid water in a closed container is an example of heterogeneous equilibrium.H2O(l)⇌H2O(g)In this example, there is a gas phase and a liquid phase. In the same way, equilibrium between two solid phases and a gas phase, can be shown as,CaCO3(s)⇌ΔCaO(s)+CO2(g)
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Which of the following reactions show(s) heterogeneous equilibria?