Q.

Which of the following reactions would give the best yield of t-butyl methyl ether?

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a

CH33C−OHConcH2SO41400C

b

CH33C−Br+CH3OH→

c

CH33C−Br+CH3ONa→

d

CH33C−OK+CH3Br→

answer is D.

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Detailed Solution

CH33C−OK+CH3Br→CH33C−O−CH3+KBrIn Williamson synthesis ether preparation alkyl halide must be 1° R-X. If 2° R-X or 3°R-X  go for elimination reaction
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Which of the following reactions would give the best yield of t-butyl methyl ether?