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Q.

Which of the following resonating structures of 1-methoxy-1, 3-butadiene is least stable?

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a

C-H2−CH=CH−CH=O⊕−CH3

b

C H2=CH−C-H−CH=O⊕−CH3

c

C-H2=CH⊕−C H−CH=O −CH3

d

C H2=CH −C-H−C⊕H=O −CH3

answer is C.

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Detailed Solution

⇒ Structures (a) and (b) are quite stable because every atom has complete octet⇒Structures (c) and (d) are less stable than (a) and (b), because in these every atom does not have complete octet.⇒Structure (d) is stabilized by resonance, which is not possible in (c).      Therefore (c) is least stable.
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