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Q.

Which of the following shows the correct decreasing order of acidic character?

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a

CH≡CH > CH3−C−CH > CH3−C ≡ C−CH3

b

CH3−C≡CH > CH≡CH > CH3−C≡C−CH3

c

CH3−C≡C−CH3 > CH3−C ≡CH > CH−C≡CH

d

CH3−C≡C−CH3 > CH≡CH>CH3−C≡CH

answer is A.

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Detailed Solution

+I effect of CH3 group opposes the removal of H-atom of −C≡C−H as H+ in case of CH3 – C ≡C – H. In case of CH3 – C≡C – CH3, H-atom of C – H combination is a part of CH3 where C-atom is sp3-hybridised. The removal of H as H+ is very difficult.
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