Which of the following shows the correct decreasing order of acidic character?
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a
CH≡CH > CH3−C−CH > CH3−C ≡ C−CH3
b
CH3−C≡CH > CH≡CH > CH3−C≡C−CH3
c
CH3−C≡C−CH3 > CH3−C ≡CH > CH−C≡CH
d
CH3−C≡C−CH3 > CH≡CH>CH3−C≡CH
answer is A.
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Detailed Solution
+I effect of CH3 group opposes the removal of H-atom of −C≡C−H as H+ in case of CH3 – C ≡C – H. In case of CH3 – C≡C – CH3, H-atom of C – H combination is a part of CH3 where C-atom is sp3-hybridised. The removal of H as H+ is very difficult.