Q.

In which of the following solutions, the solubility of AgCl will be maximum ?

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a

0.1 M AgNO3

b

0.1 M AgCl

c

water

d

NH3

answer is D.

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Detailed Solution

When NH3 is added to such an equilibrium, Ag+ (aq) are removed due to the formation of blue colored complex via the following reaction.Agaq++2NH3⇌AgNH32aq+The above equilibrium is largely fovoured forward.
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