In which of the following solvents should KCl be soluble at 25°C ?(D = Dielectric constant value)
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a
C6H6[D = 0]
b
CH3COCH3[D = 2]
c
CCl4[D = 0]
d
CH3OH[D = 32]
answer is D.
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Detailed Solution
Ionic substances are soluble in polar solvents. Greater the dielectric constant of the solvent higher will be the solubility of the ionic substance.Thus solubility of KCl inCH3OH>CH3COCH3>C6H6=CCl4