Q.

Which of the following species used both axial set of d-orbitals in hybridisation of central atom?

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a

PBr4+

b

PCl4−

c

ICl4−

d

None of these

answer is C.

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Detailed Solution

PBr4+⟶sp3PCl4−⟶sp3dICl4−⟶sp3d2
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Which of the following species used both axial set of d-orbitals in hybridisation of central atom?