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Which of the following statement is/are correct?

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a
In the lanthanide series the electrons occupy 4f-orbtals in preference to 5d the and 6p-orbitals.
b
Zero group was not present in the periodic table when Mendeleev presented it.
c
Law of octave was presented by Newland.
d
Cuprous compounds are coloured while cupric compounds are colourless

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detailed solution

Correct option is A

Statement (a) is wrong.Cu(Z=29),3d10,4s1Cu⊕( cuprous )=3d104s0Cu2+( cupric )=3d94s0(one unpaired electron and hence is coloured)

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