Which of the following statement are correct?i) In octahedral complexes, dz2,dx2−y2 orbitals have higher energy than dxy,dyz and dzx orbitalsii) In tetrahedral complexes, dxy,dyz,dzx orbitals have higher energy than dz2 and dx2−y2orbitalsiii) The colors of complexes are due to electronic transitions from one set of d-orbitals to another set of orbitals.vi) Δtetrahedral=94Δoctahedral
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a
(i),(ii) and (iii)
b
(i) and (iv)
c
(iii) and (iv)
d
(ii),(iii) and (iv)
answer is A.
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Detailed Solution
The correct relationship between tetrahedral and octahedral isΔt=49Δ0