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Q.

Which of the following statement is correct for the reaction?CaO(s)+CO2(g)⟶CaCO3(s)                                      ΔrH∘=−178.3kJmol−1

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a

ΔrH∘ is the enthalpy of formation of CaCO3

b

ΔrH∘ is not the enthalpy of formation of CaCO3

c

ΔrH∘ is the enthalpy of combustion of CaCO3

d

None of the above

answer is B.

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Detailed Solution

A standard molar enthalpy of formation, ΔfH∘ is just a special case of ΔrH∘, where one mole of a compound is formed from its constituent elements.CaO(s)+CO2(g)⟶CaCO3(s)                                     ΔrH∘=−178.3kJmol−1It is not an enthalpy of formation of CaCO3, since CaCO3 has been formed from other compounds and not from its constituent elements.
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