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a
The trichlorides of group-l3 elements, on hydrolysis form M(OH)4-
b
AlCl3 inacidifiedaqueoussolutionforms AlH2O63+
c
Boron is unreactive in crystalline form
d
boron forms a very thin hydroxide layer on its surface
answer is D.
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Detailed Solution
The trichlorides of group-l3 elements on hydrolysis form tetrahedral M(OH)4- species; the hybridization state of element M is sp3. Aluminium chloride in acidified aqueous solution forms octahedral AlH2O63+ ion. In this complex ion, the 3d -orbitals of Al are involved and the hybridization state of Al is sp3d2.Boron is unreactive in crystalline form. Aluminium forms a very thin oxide layer on its surface which protects the metal from further attack by oxygen molecules.