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Which of the following statement is wrong?

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a
A Ïƒ-bond is shorter than a Ï€-bond.
b
Bond energies of Ïƒ and Ï€ bonds are of the order of 264 and 347 kJ mol-1
c
Free rotation of atoms about a Ïƒ-bond is allowed but not in case of a Ï€-bond.
d
A Ïƒ-bond determines the direction between C-atoms but a Ï€-bond has no primary effect which leads to bonding

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detailed solution

Correct option is B

Bond energy of Ïƒ-bond is greater than that of Ï€-bond

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