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Q.

Which of the following statement is wrong for solvay process

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a

NH3 is regenerated

b

CaCl2 is one of the by product

c

CaCO3 is used completely in reaction

d

Na2CO3 is partially converted into bicarbonate

answer is D.

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Detailed Solution

2NH3 + CO2 + H2O → [NH4]2CO3[NH4]2CO3 + H2O + CO2 → 2NH4HCO3NH4HCO3 + NaCl → NH4Cl + NaHCO32NaHCO3 → Na2CO3 +CO2 + H2Oregeneration of NH3 : 2NH4Cl+CaOH2→2NH3+CaCl2ByproductNa2CO3 can't converted into bicarbonate on heating
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