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a
PbO2 reacts with HCl to evolve Cl2 gas
b
PbO2 reacts with HNO3 to evolve O2 gas
c
Pb3O4 reacts with HCl to evolve Cl2 gas
d
Pb3O4 reacts with HNO3 to form PbO2, but O2 is not liberated
answer is A.
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Detailed Solution
(1) PbO2 is a powerful oxidising agent and liberates O2 with acids. PbO2+4HCl⟶PbCl2+2H2O+Cl2 (2) PbO2+2HNO3⟶PbNO32+H2O+12O2(3) Pb3O4+8HCl⟶3PbCl2+4H2O+Cl2(4) Pb3O4+4HNO3⟶PbNO32+PbO2+2H2O