Q.

Which of the following statements are correct?

Moderate

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By Expert Faculty of Sri Chaitanya

A NaCl type is f.c.c. unit cells with corners and faces occupied by either cation or anion

In a face-centred cubic unit cell, the body centre is an octahedral void

In f. c. c. unit cell, octahedral and tetrahedral voids are equal

Tetrahedral voids = 2 × octahedral voids, is true for only c. c. p and h. c. p.

answer is 1,2,4.

(Detailed Solution Below)

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Detailed Solution

f c c has cations occupying corners and faces ,anions occupying body center and edge centers and vice versa

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