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Questions  

Which of the following statements are correct?

a) +I group stabilizes a carbocation

b) + I group stabilizes a carbanion

c) - I group stabilizes a carbocation

d) - I group stabilizes a carbanion

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By Expert Faculty of Sri Chaitanya
a
Both a, b
b
Both a, c
c
Both a, d
d
Both b,d

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detailed solution

Correct option is C

Stability order:–IE groups increases the stability of carbanion.As the no of -IE [Alkyl groups] groups increasestability of carbanion increases,Stability order:+IE group increases the electron density on carbanion carbon and hence decreases the stability of carbanion.→ As the no of +IE groups increases stability of carbanion decreases.Stability order:–IE groups increases the positive charge on carbocation carbonand hence decreases the stability of carbanion.→ As the no –IE groups increases stability of carbocation decreases.


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Increasing order of stability of the following carbocations

C+H3I ,C+D3II , C+T3III

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